代表性教学科研项目： 1、非贵金属（Mn, Fe, Co, Ni）配合物催化剂设计，合成及催化活性研究，21801158，2019/01-2021/12，国家自然科学基金青年基金，主持。 2、基于产学研的传感技术用于重金属离子污染监测实践基地建设，202101237036，教育部产学合作协同育人项目，2021/04-2023/03，主持。 3、MOFs负载单位点廉价金属催化剂的设计合成及催化研究，2020/8-2022/07，2020年青岛市博士后应用研究项目，主持。 4、基于MOFs负载单位点催化剂的合成及其应用研究，QUTSEME201934，2019/11-2021/11，青岛理工大学环境科学与工程一流学科开放课题，主持。 5、纳米纤维素纸基电致化学发光新体系及其生物传感应用，KF2020201，2020/12-2022/12，青岛大学省部共建生物多糖纤维成形与生态纺织国家重点实验室开放课题面上项目，主持。
代表性论文： [1] T. Yan, G. Zhang, K. Yu, H. Chai, M. Tian, L. Qu, H. Dong, X. Zhang, Smartphone light-driven zinc porphyrinic MOF nanosheets-based enzyme-free wearable photoelectrochemical sensor for continuous sweat vitamin C detection, Chem. Eng. J., 2023, 10.1016/j.cej.2022.140779. [2] H. Chai, Y. Ma, Z. Yuan, Y. Li, G. Liu, L. Chen, Y. Tian, W. Tan, J. Ma, G. Zhang*, A ratiometric fluorescence sensor based on carbon dots and two-dimensional porphyrinic MOFs for on-site monitoring of sulfide, Microchem. J. 2023, 185, 108288. [3] Y. Lu, H. Chai*, K. Yu, C. Huang, Y. Li, J. Wang, J. Ma, W. Tan*, G. Zhang, A reusable MOF supported single-site nickel-catalyzed direct N-alkylation of anilines with alcohols, Tetrahedron, 2022, 124, 132993. 132993. [4] A. Boakye, K. Yu, B. K. Asinyo, H. Chai, T. Raza, T. Xu, G. Zhang*, L. Qu, A Portable Electrochemical Sensor Based on Manganese Porphyrin-Functionalized Carbon Cloth for Highly Sensitive Detection of Nitroaromatics and Gaseous Phenol, Langmuir 2022, 38, 1205. [5] K. Yu, M. Li, H. Chai, Q. Liu, X. Hai, M. Tian, L. Qu, T. Xu, G. Zhang*, X. Zhang, MOF-818 nanozyme-based colorimetric and electrochemical dual-mode smartphone sensing platform for in situ detection of H2O2 and H2S released from living cells. Chem. Eng. J., 2023, 451, 138321. [6] G. Zhang, Y. Ma, H. Chai*, K. Yu, Y. Li, S. Wang, J. Ma, L. Qu, W. Tan*, X. Zhang, Porphyrinic metal–organic framework@alumina nanocomposite fluorescent probe: Two-stage stimuli-responsive behavior and phosphate sensing, Sens. Actuators B Chem. 2022, 370, 132395. [7] G. Zhang*, K. Yu, B. Zhou, J. Wang, C. Zheng, L. Qu, H. Chai*, X. Zhang, Magnetic zirconium-based Prussian blue analog nanozyme: Enhanced peroxidase-mimicking activity and colorimetric sensing of phosphate ion, Microchim. Acta, 2022, 189, 220. [8] K. Yu, G. Zhang*, H. Chai, L. Qu, D. Shan, X. Zhang*, Two-stage ligand exchange in Mn(III)-based porphyrinic metal−organic frameworks for fluorescence water sensing, Sens. Actuators B Chem. 2022, 362, 131808. [9] Y. Bai, L. Xu, H. Chai, L. Zhou, G. Jiang, G. Zhang*, Recent Advances on DNAzyme-Based Biosensors for Detection of Uranyl, Front. Chem. 10 (2022), 882250. doi: 10.3389/fchem.2022.882250. [10] M. Li, G. Zhang*, A. Boakye, H. Chai*, L. Qu*, X. Zhang, Recent Advances in Metal-Organic Framework-Based Electrochemical Biosensing Applications, Front. Bioeng. Biotechnol. 9 (2021), 797067. [11] T. Yan, G. Zhang*, H. Chai, L. Qu*, X. Zhang, Flexible Biosensors Based on Colorimetry, Fluorescence, and Electrochemistry for Point-of-Care Testing, Front. Bioeng. Biotechnol. 9 (2021), 753692. [12] G. Y. Zhang*, M. J. Li, K. Yu, H. N. Chai*, S. H. Xu, T. L. Xu, L. J. Qu, X. J. Zhang*, Two-Dimensional Metalloporphyrinic Framework Nanosheet-Based Dual-Mechanism-Driven Ratiometric Electrochemiluminescent Biosensing of Protein Kinase Activity, ACS Appl. Bio Mater. 2021, 4, 161. [13] H. N. Chai *, G. Y. Zhang, W. Q. Tan*, J. P. Ma, A robust NNP-type ruthenium(II) complex for alcohols dehydrogenation to esters and pyrroles. Appl. Organometal. Chem. 2020, 34, e5367. [14] H. N. Chai *, K. Yu, B. Liu, W. Q. Tan, G. Y. Zhang, A Highly Selective Manganese-Catalyzed Synthesis of Imines under Phosphine-Free Conditions. Organometallics, 2020, 39, 217. [15] H. N. Chai *, W. Q. Tan, Y. Y. Lu, G. Y. Zhang*, J. P. Ma, Sustainable synthesis of quinolines (pyridines) catalyzed by a cheap metal Mn(I)-NN complex catalyst. Appl. Organometal. Chem. 2020, 34, e5685. [16] G. Y. Zhang*, H. N. Chai, M. W. Tian, S. F. Zhu, L. J. Qu, X. J. Zhang*, Zirconium-Metalloporphyrin Frameworks-Luminol Competitive Electrochemiluminescence for Ratiometric Detection of Polynucleotide Kinase Activity, Anal. Chem. 2020, 92, 7354. [17] Q. F. Wang#, H. N. Chai#, Z. K. Yu,* Acceptorless Dehydrogenation of N-Heterocycles and Secondary Alcohols by Ru(II)-NNC Complexes Bearing a Pyrazoyl-Indolyl-Pyridine Ligand. Organometallics 2018, 37, 584.（共同一作） [18] H. N. Chai, T. T. Liu, Z. K. Yu,* NHTs Effect on the Enantioselectivity of Ru(II) Complex Catalysts Bearing a Chiral Bis(NHTs)-Substituted Imidazolyl-Oxazolinyl-Pyridine Ligand for Asymmetric Transfer Hydrogenation of Ketones. Organometallics 2017, 36, 4136. [19] H. N. Chai, T. T. Liu, D. Y. Zheng, Z. K. Yu,* Cooperative N-H and CH2-Skeleton Effects on the Catalytic Activities of Bimetallic Ru(II)-NNN Complexes: Experimental and Theoretical Study. Organometallics 2017, 36, 4268. [20] H. N. Chai, L. D. Wang, T. T. Liu, Z. K. Yu,*A Versatile Ru(II)-NNP Complex Catalyst for the Synthesis of Multisubstituted Pyrroles and Pyridines. Organometallics 2017, 36, 4936. [21] H. N. Chai, Q. F. Wang, T. T. Liu, Z. K. Yu,* Diruthenium(II)-NNN Pincer Complex Catalysts for Transfer Hydrogenation of Ketones. Dalton Trans. 2016, 45, 17843. [22] H. N. Chai, T. T. Liu, Q. F. Wang, Z. K. Yu,* Substituent Effect on the Catalytic Activity of Ru(II) Complexes Bearing a Pyridyl-Supported Pyrazolyl-Imidazolyl Ligand for Transfer Hydrogenation of Ketones. Organometallics 2015, 34, 5278. [23] 李钰杰，柴会宁*，卢媛媛，谭伟强，马继平，张光耀∗，张学记，基于金属有机框架材料的光/电化学传感器在水环境检测中的应用进展，分析化学，2021, 10, 1619. [24] 柴会宁*，刘波，刘爱芹，喻琨，非贵金属（Mn, Co, Fe）配合物催化醇类脱氢偶联/缩合反应研究进展, J. mol. Catal. (China) 2018, 32(5), 481-491. (in Chinese) 代表性专利： 1、 发明专利名称：一种MOF-on-MOF材料的合成方法与毒死蜱检测的应用，申请号：2023100421762。 2、发明专利名称：一种双阶段刺激-响应型的卟啉MOF@氧化铝纳米复合物荧光探针用于磷酸根的检测，申请号：202210390027。 3、发明专利名称：一种MXene基纳米酶复合物的合成与有机磷农药检测的应用，申请号：202211422646X。 4、专利授权：吡啶基桥联NNP钴配合物及其应用，专利号：ZL 202011102276.2。
|
